Cuicui Yang, Mengjie Chen, Yijun Qian et al.

Science China Materials • 2018

M.J. Salar-García, Xavier Alexis Walter, Jonas Gurauskis et al.

Electrochimica Acta • 2020

Ceramic materials based on naturally occurring clays are a low cost and environmentally friendly alternative to commercial polymer-based membranes in bioelectrochemical systems. In this work, ceramic membranes containing different amounts of iron oxide (1.06, 2.76 and 5.75 vol.%) and sintered at different temperatures (1100, 1200 and 1300 °C) have been elaborated and tested as separators in urine-fed microbial fuel cells (MFCs). The results reveal that the presence of iron oxide in the ceramic membrane composition increases the structural porosity and reduces the pore size for the three temperatures investigated. On the other hand, it was also observed that the iron content mitigates the negative effect of the high sintering temperature on the power performance of the MFCs. In the case of the ceramic membranes sintered at 1300 °C, power output improved ca. 10-fold when the iron oxide content in the membrane increased from 1.06 up to 5.75 vol.% (30.9 and 286.6 µW, respectively). Amongst the different combinations of iron phase content and sintering temperatures, the maximum power output was obtained by MFCs working with separators containing 5.75 vol. % of iron oxide and sintered at 1100 °C (1.045 mW). Finally, the system was stable for 65 days, which supports the long-term functionality of the different materials assessed.

M. Emran Khan, Agung Wibowo, Zoheb Karim et al.

Polymers • 2024

Huge amounts of noxious chemicals from coal and petrochemical refineries and pharmaceutical industries are released into water bodies. These chemicals are highly toxic and cause adverse effects on both aquatic and terrestrial life. The removal of hazardous contaminants from industrial effluents is expensive and environmentally driven. The majority of the technologies applied nowadays for the removal of phenols and other contaminants are based on physio-chemical processes such as solvent extraction, chemical precipitation, and adsorption. The removal efficiency of toxic chemicals, especially phenols, is low with these technologies when the concentrations are very low. Furthermore, the major drawbacks of these technologies are the high operation costs and inadequate selectivity. To overcome these limitations, researchers are applying biological and membrane technologies together, which are gaining more attention because of their ease of use, high selectivity, and effectiveness. In the present review, the microbial degradation of phenolics in combination with intensified membrane bioreactors (MBRs) has been discussed. Important factors, including the origin and mode of phenols' biodegradation as well as the characteristics of the membrane bioreactors for the optimal removal of phenolic contaminants from industrial effluents are considered. The modifications of MBRs for the removal of phenols from various wastewater sources have also been addressed in this review article. The economic analysis on the cost and benefits of MBR technology compared with conventional wastewater treatments is discussed extensively.

Tonoy Chowdhury, Lei Zhang, Junqing Zhang et al.

Nanomaterials • 2018

MIL-53(Al)-graphene oxide (GO) nanocomposites of different GO to MIL-53(Al) mass ratios (1% to 25% GO) were synthesized and tested for removal of arsenite (As(III)), which is a well-known groundwater contaminant. The properties of MIL-53(Al)-GO nanocomposites were characterized using X-ray Diffraction (XRD), Fourier Transform Infrared (FT-IR) Spectroscopy, Brunauer-Emmett-Teller (BET) surface area measurements, and Scanning Electron Microscopy (SEM). Batch experiments were performed on MIL-53(Al)-GO nanocomposites for As(III) adsorption in aqueous solutions to investigate adsorption kinetics and isotherm behavior under varying environmental conditions. The effects of solution pH (2 to 11), initial As(III) concentrations (10⁻110 mg/L), adsorbent dosage (0.2⁻3.0 g/L), and temperature (298⁻318 K) on As(III) adsorption were investigated. MIL-53(Al)-GO nanocomposites showed higher adsorption of As(III) than pristine MIL-53(Al) and GO individually. As (III) removal was optimized at a ratio of 3% GO in the MIL-53(Al)-GO nanocomposite, with an adsorption capacity of 65 mg/g. The adsorption kinetics and isotherms followed pseudo-second-order and Langmuir isotherm models, respectively. Overall, these results suggest that MIL-53(Al)-GO nanocomposite holds a significant promise for use in the remediation of As (III) from groundwater and other aqueous solutions.

Gouranga Dutta, Santosh kumar Chinnaiyan, Abimanyu Sugumaran et al.

RSC Advances • 2023

Cancer, microbial infections, and water pollution are significant challenges the modern human population faces. Traditional treatments for cancer and infections often have adverse effects and ecological consequences, while chemical methods for water decontamination can produce harmful byproducts. Metal nanoparticles, particularly zinc oxide (ZnO) and silver (Ag) nanoparticles, show promise in addressing these issues. However, doping Ag on ZnO NPs may synergistically enhance biomedical and therapeutic effects with fewer adverse consequences and improved photocatalytic properties for wastewater treatment. This study aimed to create ZnO and ZnO-Ag nanoparticles through green synthesis and compare their anticancer, antimicrobial, and photocatalytic activity mechanisms. XRD studies determined the crystal diameters of ZnO NPs and ZnO-Ag NPs to be 12.8 nm and 15.7 nm, respectively, with a hexagonal wurtzite structure. The XPS and EDS analyses confirmed the presence of Ag on the ZnO NPs. ZnO NPs and ZnO-Ag NPs exhibited low aggregation in aqueous suspensions, with zeta potentials of -20.5 mV and -22.7 mV, respectively. Evaluating antimicrobial and antibiofilm activity demonstrates that ZnO-Ag NPs have superior potential to ZnO NPs and standard antibiotic drugs against E. coli , S. typhi , B. subtilis , S. aureus , C. albicans , and A. niger . The results of the in vitro cytotoxicity test indicated that on the NCI-H460 lung cancer cell line, ZnO NPs and ZnO-Ag NPs demonstrated IC 50 values of 40 μg mL -1 and 30 μg mL -1 , respectively. The photocatalytic degradation of methylene blue under direct sunlight revealed that ZnO and ZnO-Ag NPs degraded MB by 98% and 70% in 105 min, respectively. These results show that these nanomaterials may have great potential for treating the aforementioned issues.

Musarat Amina, Nawal M. Al Musayeib, Nawal A. Alarfaj et al.

PLoS ONE • 2020

Distinct morphological MgO nanoparticles (MgONPs) were synthesized using biomasses of Saussurea costus roots. The biomass of two varieties of Saussurea costus (Qustal hindi and Qustal bahri) were used in the green synthesis of MgONPs. The physical and chemical features of nanoparticles were confirmed by spectroscopic and microscopic techniques. The surface morphology of the obtained nanoparticles was detected at different magnifications by SEM and TEM microscopy and the size of nanoparticles were found to be 30 and 34 nm for Qustal hindi and Qustal bahri, respectively. The antimicrobial activity of the prepared MgONPs was screened against six pathogenic strains. The synthesized nanoparticles by Qustal bahri biomass exerted significant inhibition zones 15, 16, 18, 17, 14, and 10 mm against E. coli, P. aeruginosa, C. tropicalis and C. glabrata, S. aureus and B. subtilis as compared to those from Qustal hindi 12, 8 and 17 mm against B. subtilis, E. coli and C. tropicalis, respectively. MgONPs showed a potential cytotoxicity effect against MCF-7 breast cancer cell lines. Cellular investigations of MgONPs revealed that the prepared nanoparticles by Qustal bahri exhibited high cytotoxicity against MCF-7 cancer cell lines. IC50 values in MCF-7 cells were found to be 67.3% and 52.1% for MgONPs of Saussurea costus biomasses, respectively. Also, the photocatalytic activity of MgONPs of each Saussurea costus variety was comparatively studied. They exhibited an enhanced photocatalytic degradation of methylene blue after UV irradiation for 1 h as 92% and 59% for those prepared by Qustal bahri and Qustal hindi, respectively. Outcome of results revealed that the biosynthesized MgONPs showed promising biomedical potentials.

Eric Mutegoa

Discover Water • 2024

The rise in the world's population has led to an amplified need for fundamental requirements such as healthcare, shelter, and water. At the same time, human practices like agriculture, mining, and deforestation have resulted in challenges related to environmental sustainability and the contamination of water resources. As a result, access to safe drinking water has become a major challenge worldwide, and controlling water pollution is crucial. Several water treatment methods, including adsorption, nanotechnology, and membrane technology, have been developed to mitigate health and environmental impacts. However, many of these methods are too expensive, especially for people living in low-income countries. Additionally, some of the technologies are not very effective at removing pollutants, which exacerbates the problem. The physical, chemical, and biological approaches for treating water are categorized in this review, along with the benefits and drawbacks of each approach. Given that the adsorption method is thought to be one of the more economical and environmentally friendly techniques to treat water, this review recommends that in order to increase the efficacy of the adsorbents, a comprehensive investigation into the exact operation of the adsorbents at the cellular and molecular levels be conducted.

Neha Tavker, Virendra Kumar Yadav, Krishna Kumar Yadav et al.

Polymers • 2021

Nano-fibrillated cellulose (NFC) was extracted by a chemical method involving alkali and acid hydrolysis. The characterisation of the citrus sinensis fruit peel bran and nano-fibrillated cellulose was performed by XRD, FTIR, TEM, and FESEM. XRD confirmed the phase of NFC which showed monoclinic crystal with spherical to rod shape morphology with a size of 44-50 nm. The crystallinity index of treated NFC increased from 39% to 75%. FTIR showed the removal of lignin and hemicellulose from waste peels due to the alkaline treatment. Silver nanoparticles were also synthesised by utilizing extract of citrus sinensis skins as a reducing agent. Pharmaceutical effluent samples from an industrial area were tested by Atomic Absorption Spectrometry. Out of the four metals obtained, cadmium and chromium were remediated by silver nanoparticles with nano-fibrillated cellulose via simulated method in 100 mg/L metal-salt concentrations over a time period of 160 min. The highest removal efficiency was found for cadmium, i.e., 83%, by using silver and NFC together as adsorbents. The second highest was for chromium, i.e., 47%, but by using only NFC. The Langmuir and Freundlich isotherms were well fitted for the sorption of Cd (II) and Cr (II) with suitable high R 2 values during kinetic simulation. Thus, the isolation of NFC and synthesis of silver nanoparticles proved efficient for heavy metal sorption by the reuse of waste skins.

Pimprapa Chaijak, Chikashi Sato, Monthon Lertworapreecha et al.

Polish Journal of Environmental Studies • 2019

A cost-effective biochar derived from rubber tree sawdust was prepared by low-temperature pyrolysis at 500C for 2 h. The biochar was placed as an anode electrode in the anode chamber of the novel model ceramic-separator microbial fuel cell (CMFC) with a laccase-based air cathode. The rubber wastewater (with 500 mg/L sulfate and 1000 mg/L COD) was used as an anolyte. Maximal volumetric power density (PD) of 3.260.08 W/m 3 , maximal volumetric current density of 3.200.07 mA/m 3 , and system internal resistance of 1002 were obtained. The post-treatment results showed sulfate removal and COD removal efficiencies of 88.261.29% and 89.770.45%, respectively. Our work provided a novel model of a low-cost and economically friendly MFC system. Moreover, this work demonstrated a potential route based on sustainable and economical biochar as a bio-anode for wastewater treatment in an MFC.

Heli Patel, Virendra Kumar Yadav, Krishna Kumar Yadav et al.

Water • 2022

The textile industry generated a series of synthetic dyestuffs that threatened environmental protection. Azo dyes, widely utilized in textile, paper, fruit, leathers, cosmeceuticals and pharmaceutical fields, account for most of the dyestuffs made. Since they have colour fastness properties, stability, and susceptibility to oxidation, existing effluent treatment methods cannot entirely strip different dyes from effluents. Under certain environmental factors, bacteria decolourize and degrade dyes. The treatment process is cheap, environmentally safe, and can be used on various dyes. However, textile plant wastewater can produce many polluting chemicals and dyes. Environmental legislation is increasingly being enacted to regulate mainly azo-based dyes in the environment. The potential of the microbes for the decolourization of dyes and metabolizing them is long-known knowledge. The toxic components of dyes challenge a potential threat to all the living forms of life. Though both natural and synthetic dyes are used for the colourization of textiles, only synthetic ones are challenging to decolourize. Microbial-based bioremediation of dyes has been studied and reviewed primarily to accelerate dye degradation. The various piece of the literature revealed that the majority of these dye removal microbes belong to mainly white-rot fungi, a consortium of anaerobic bacteria. In addition to this, there are several (genetically engineered microorganisms) GEMs that remediate dyes efficiently. Here in the current review, the authors have tried to bridge the existing gap in the bioremediation of dyestuff. Moreover, the authors have also tried to provide the latest trend in this field. This study will surely benefit the industries and researchers related to dyestuffs by maintaining eco-friendly approaches.

Hongxiang Xie, Haishun Du, Xianghao Yang et al.

International Journal of Polymer Science • 2018

The recent strategies in preparation of cellulose nanocrystals (CNCs) and cellulose nanofibrils (CNFs) were described. CNCs and CNFs are two types of nanocelluloses (NCs), and they possess various superior properties, such as large specific surface area, high tensile strength and stiffness, low density, and low thermal expansion coefficient. Due to various applications in biomedical engineering, food, sensor, packaging, and so on, there are many studies conducted on CNCs and CNFs. In this review, various methods of preparation of CNCs and CNFs are summarized, including mechanical, chemical, and biological methods. The methods of pretreatment of cellulose are described in view of the benefits to fibrillation.

Jonathan Morris, Ioannis Y. Georgiou, Edeltraud Guenther et al.

Circular Economy and Sustainability • 2021

Abstract The business case for circular economy in water management perspective has gain relevance in the recent times. By 2030, it is estimated that 160% of global total available water will be required to satisfy demand of anthropogenic-related activities and increasing waste-related water will be produced. Gaps on the conceptual framing of water reuse within supply chain management are clearly emerging and the demand for decision support systems helping at assessing effective water consumption in industrial setting is pressing. Despite the numerous local initiatives towards wastewater resource usage, barriers remain for its implementation in practice. Through a systematic review of previous studies in this field, the barriers towards the uptake of wastewater use in agriculture were classified according to the PESTEL (political, economic, social, technological, environmental and legal) framework. Alongside political and legal support, it is identified that for an economically and environmentally sustainable scheme for incentivising the deployment of feasible technologies, there is also a need to gain acceptance for wastewater usage in society in order to enhance the deployment of existing technological solutions. Addressing these factors in tandem can aid the development towards a circular economy for wastewater.

Md Ekhlasur Rahman, Mohd Izuan Effendi Halmi, Mohd Yusoff Bin Abd Samad et al.

International Journal of Environmental Research and Public Health • 2020

Constructed wetlands (CWs) are affordable and reliable green technologies for the treatment of various types of wastewater. Compared to conventional treatment systems, CWs offer an environmentally friendly approach, are low cost, have fewer operational and maintenance requirements, and have a high potential for being applied in developing countries, particularly in small rural communities. However, the sustainable management and successful application of these systems remain a challenge. Therefore, after briefly providing basic information on wetlands and summarizing the classification and use of current CWs, this study aims to provide and inspire sustainable solutions for the performance and application of CWs by giving a comprehensive review of CWs' application and the recent development of their sustainable design, operation, and optimization for wastewater treatment. To accomplish this objective, thee design and management parameters of CWs, including macrophyte species, media types, water level, hydraulic retention time (HRT), and hydraulic loading rate (HLR), are discussed. Besides these, future research on improving the stability and sustainability of CWs are highlighted. This article provides a tool for researchers and decision-makers for using CWs to treat wastewater in a particular area. This paper presents an aid for informed analysis, decision-making, and communication. The review indicates that major advances in the design, operation, and optimization of CWs have greatly increased contaminant removal efficiencies, and the sustainable application of this treatment system has also been improved.

Amer M. Abdelaziz, Salem S. Salem, Ahmed Mohamed Aly Khalil et al.

BioMetals • 2022

In this study, a novel, non-toxic, eco-friendly zinc oxide nanoparticles (ZnO-NPs) was used instead of the synthetic fungicides widely used to control the destructive phytopathogenic fungus Fusarium oxysporum, the causative agent of wilt disease in Solanum melongena L. Herein, the biosynthesized ZnO-NPs was carried out by Penicillium expansum ATCC 7861. In vitro, mycosynthesized ZnO-NPs exhibited antifungal activity against Fusarium oxysporum. In vivo, ZnO-NPs suppressed Fusarium wilt disease in cultivated Solanum melongena L. by decreasing the disease severity with 75% of plant protection. Moreover, ZnO-NPs stimulated the recovery of eggplant as an indicated by improving of morphological and metabolic indicators including plant height(152.5%), root length(106.6%), plant fresh biomass (146%), chlorophyll a (102.8%), chlorophyll b (67.86%), total soluble carbohydrates (48.5%), total soluble protein (81.8%), phenol (10.5%), antioxidant activity and isozymes compared with infected control. Therefore, this study suggests using mycosynthesized ZnO-NPs as an alternative to synthetic fungicides not only to eradicate the Fusarium wilt disease in cultivated eggplant (Solanum melongena) but also to promote the growth parameters and metabolic aspects.

Ikrema Hassan, Saidur Rahman Chowdhury, Perdana K. Prihartato et al.

Processes • 2021

Constructed wetlands (CW) is an environmentally friendly technique for removing pollutants from wastewater and has been applied to municipal wastewater, petroleum refinery wastewater, agriculture drainage, acid mine drainage, etc. The past decade has seen a remarkable number of innovations in the exponentially growing field of microbiology. This manuscript covers a critical review of key aspects of CW, such as various types of CW, the contaminants and their removal mechanisms, degradation pathways, challenges and opportunities, materials, applications, and theory with a focus on recent advances in the last three decades. In addition, an attempt has been taken to project future advances in the field of CW and facilitate these advances by framing key unsolved problems in CW. Guidelines are prepared for the fast-growing CW field through the standardization of key design aspects. This review covers the evaluation of the current state-of-the-art of CW technology and provides definitions and performance metric nomenclature in an effort to unify the fast-growing CW community. It also contains an outlook on the emerging trends in CW and proposes future research and development directions.

Hanane Afanga, Hicham Zazou, Fatima Ezzahra Titchou et al.

Sustainable Environment Research • 2020

Abstract Textile wastewater containing toxic dyes needs efficient treatment before being released into the environment. Certain dyes are known or presumed to have carcinogenic potential for humans. In this work, hybrid electrochemical processes including electrocoagulation (EC) alone and combined with electro Fenton (EF), anodic oxidation (AO) and peroxi-coagulation (PC) were tested to treat real textile wastewater using a batch reactor. A sequential EC and EF (EC-EF) process was found to be more effective. The experimental results indicated that the effectiveness of the treatment decreases in the following order: EC-EF > EC-AO > EC-PC > EC. EC-EF results showed a decrease in chemical oxygen demand (COD, 97%), total organic carbon (98%), total suspended solids (98%), and the concentration of metal species; showing that the treatment of such wastewater type can be achieved by combined EC-EF process in a one-pot bench-scale reactor. The electrical energy consumption, the iron dissolution, and the biological oxygen demand/COD ratios of EC and EC-EF processes were evaluated. Characterization of the sludge generated during EC treatment at current density of 20 mA cm − 2 was carried out. Precipitation, adsorption, and electrochemical oxidation/reduction of organic dyes and metallic ions occurred during the treatment. This investigation shows the efficiency of combined EC-EF to treat textile wastewater.

Sharifah Mohammad, Siti Baidurah, Takaomi Kobayashi et al.

Processes • 2021

Ponding system or land application techniques are widely used at industrial scale to treat palm oil mill effluent (POME) prior to discharge to the environment. POME is considered as one of the major problems that has generated voluminously from the palm oil industries. The main purpose of this article is to organize the scattered available information on various aspects and a wide range of promising current POME treatments including biological microorganisms, physicochemical methods of coagulation, and membrane and thermochemical process. In addition, the integrated system of anaerobic-aerobic bioreactor (IAAB), which has been touted as highly efficient with easy control at acceptable temperature range and shorter treatment time, has potential to be exploited for POME treatment. The main influencing factors for IAAB POME treatment are highlighted as outstanding characteristics for challenges and future prospects.

Imran Ahmad, Dilawar Husain

Journal of the Indian Chemical Society • 2024

The microbial fuel cell (MFC) powered dual cathode electro-Fenton (DCEF) advanced oxidation process was used for the Reactive Orange 16 (RO16) dye treatment. As MFC is known for its high membrane costs and low power densities, we used a single-chamber MFC with anodic cell exposure to air to limit the substrate loss caused by the methanogenesis activity and achieve higher power output. The developed MFC shows 672.20 mW/m3 of maximum volumetric power density (Pmax). Although, the developed MFCs generate renewable energy from wastewater; the resulting power is too low for any practical application. Therefore, we designed here a newly developed low-voltage booster (LVB) to extract useful power. With the low output, the MFC voltage (around 0.4 V) was effectively increased to 12.2 ± 0.02 V without experiencing any voltage reversal problems. Furthermore, even after detaching the LVB from the MFC, the boosted voltage (12.2 ± 0.02 V) was consistently maintained for more than 10 hours. We believe that this type of low voltage booted electrical circuit MFC-powered system will offer a more energy-efficient and economical method for treating textile industrial dye pollutants.

Hongtao Wang, Yi Yang, Arturo A. Keller et al.

Applied Energy • 2016

H. Elhosiny Ali, Hoda H. El-Hendawy, Mohamed Azab El‐Liethy et al.

International Journal of Biological Macromolecules • 2025

Julius Nnamdi Ndive, Simeon Okechukwu Eze, Somtochukwu Godfrey Nnabuife et al.

Waste Management Bulletin • 2025

• Dual-chamber MFC enables azo dye degradation and electricity generation. • Electrochemically active strains isolated from azo-dye-contaminated soil. • UV–Vis spectroscopy confirms significant azo bond cleavage in wastewater. • Peak MFC output of 0.20 mV voltage and 0.16 mA current over eight days. • NaCl addition enhances ionic conductivity, improving MFC system performance. Textile wastewater, particularly azo dyes, poses significant environmental challenges due to its poor biodegradability and toxicity. This study explores a dual-chamber microbial fuel cell (MFC) for simultaneous wastewater treatment and electricity generation. The MFC consists of an anaerobic anode chamber and an aerobic cathode chamber, separated by a proton exchange membrane (PEM). Electroactive microorganisms in the anode chamber metabolize organic substrates, including azo dye contaminants, breaking them down into simpler by-products. Electrons released during this process flow through an external circuit to generate current, while protons migrate across the PEM to the cathode chamber for oxygen reduction. Electrochemically active microbes were isolated from azo-dye-contaminated soil, and their degradation abilities validated through assays. Optimized carbon-based electrodes and a Nafion 117 PEM were used to enhance conductivity and microbial activity. UV–Vis spectroscopy tracked dye degradation, with the absorbance peak of reactive yellow dye at 410 nm decreasing from 2.9 to 0.4, indicating effective azo-bond cleavage. The MFC achieved peak voltage and current outputs of 0.20 mV and 0.16 mA, respectively, demonstrating its dual functionality. Adding NaCl as a supporting electrolyte further improved ionic conductivity and performance. This study demonstrates MFC technology as a sustainable solution for industrial wastewater challenges, integrating microbial degradation with bioelectricity generation. Future work should address scalability, operational stability, and advanced electrode designs to enhance its practical applications.

Timoth Mkilima, Yerkebulan Zharkenov, Aisulu Abduova et al.

Journal of King Saud University - Engineering Sciences • 2025

Abstract Textile wastewater poses significant environmental challenges due to high concentrations of organic matter, nitrogen, phosphorus, and persistent pollutants. Innovative and sustainable treatment technologies are crucial to mitigate these issues while minimising energy consumption and enhancing resource recovery. This study investigated a hybrid wastewater treatment system integrating a dual-chamber microbial fuel cell (MFC) with a Photo-Fenton advanced oxidation process (AOP). Continuous flow experiments were conducted at a laboratory scale using graphite felt electrodes and a high-organic-load acclimated microbial consortium. The hybrid system demonstrated high removal efficiencies: chemical oxygen demand (COD) (92.3%), biochemical oxygen demand (BOD) (95.1%), total nitrogen (TN) (73.8%), and total phosphorus (TP) (81.6%), alongside significant energy recovery (342 mW/m 2 peak power density). Notably, the MFC stage achieved dye degradation of 58.7%, highlighting its capability in preliminary pollutant remediation. Subsequent AOP treatment further reduced dye concentrations to below detection limits (< 0.5 mg/L), achieving high degradation efficiency exceeding 98%. Energy metrics revealed a stable electrochemical performance with a voltage output of 0.51 ± 0.03 V and a modest Coulombic efficiency (CE) of 18.4%, suitable for real-world industrial applications. Microbial community analysis indicated significant shifts in diversity and functionality across treatment stages, underscoring their role in pollutant degradation and system performance enhancement. This integrated MFC–Photo-Fenton system not only offers efficient wastewater treatment and energy recovery but also represents a sustainable approach to addressing complex textile effluents. These findings provide valuable insights into advancing hybrid biological–chemical processes for decentralised wastewater treatment in industrial settings.

Sing-Mei Tan, Li‐Ngee Ho, Yee‐Shian Wong et al.

Journal of Environmental Management • 2024

Hadi Seddiqi, Erfan Oliaei, Hengameh Honarkar et al.

Cellulose • 2021

Abstract Cellulose is the most abundant polysaccharide on Earth. It can be obtained from a vast number of sources, e.g. cell walls of wood and plants, some species of bacteria, and algae, as well as tunicates, which are the only known cellulose-containing animals. This inherent abundance naturally paves the way for discovering new applications for this versatile material. This review provides an extensive survey on cellulose and its derivatives, their structural and biochemical properties, with an overview of applications in tissue engineering, wound dressing, and drug delivery systems. Based on the available means of selecting the physical features, dimensions, and shapes, cellulose exists in the morphological forms of fiber, microfibril/nanofibril, and micro/nanocrystalline cellulose. These different cellulosic particle types arise due to the inherent diversity among the source of organic materials or due to the specific conditions of biosynthesis and processing that determine the consequent geometry and dimension of cellulosic particles. These different cellulosic particles, as building blocks, produce materials of different microstructures and properties, which are needed for numerous biomedical applications. Despite having great potential for applications in various fields, the extensive use of cellulose has been mainly limited to industrial use, with less early interest towards the biomedical field. Therefore, this review highlights recent developments in the preparation methods of cellulose and its derivatives that create novel properties benefiting appropriate biomedical applications.

Sai Zhang, Shiyu Zhang, Hao Liu et al.

Journal of environmental chemical engineering • 2023

Monali Muduli, Meena Choudhary, Vasavdutta Sonpal et al.

Sustainable Water Resources Management • 2023

Deepika Sheoran, Simranjeet Singh

Environmental Science and Pollution Research • 2024

Yinghao Huang, Boyue Liu, Yiyang Chi et al.

Journal of Water Process Engineering • 2024

Monali Muduli, Amit Chanchpara, Meena Choudhary et al.

Sustainable Water Resources Management • 2022

Kristina Joksimović, Igor Kodranov, Danijela Randjelović et al.

Bioelectrochemistry • 2022

Masoom Fatima, Yohannes Kiros, Robina Farooq et al.

Frontiers in Energy Research • 2021

A flow through anaerobic microbial fuel cell (MFC) was designed and optimized for efficient treatment of recalcitrant textile wastewater. The membrane-less MFC was first time fabricated with a unique combination of electrodes, a novel bioanode of synthesized lignin-based electrospun carbon fiber supporting a biofilm of Geobacter sulfurreducens for acetate oxidation and an air-breathing cathode, consisting of a pyrolyzed macrocycle catalyst mixture on carbon bonded by polytetrafluoroethylene (PTFE). The effects of different organic loadings of acetate along with Acid Orange (AO5), operation time and ionic strength of auxiliary salts (conductivity enhancers) were investigated and responses in terms of polarization and degradation were studied. In addition, the decomposition of the organic species and the degradation of AO5 along with its metabolites and degraded products (2-aminobenzenesulfonic acid) were determined by chemical oxygen demand (COD) analysis, UV-Vis spectrophotometry and high-performance liquid chromatography (UV-HPLC) techniques. SEM and TEM images were also used to find out the biocompatibility of the microbes on lignin-based electrospun carbon felt anode and the morphology of the cathode. Reduction and breakage of the azo bond of AO5 occurs presumably as a side reaction, resulting in the formation of 2-aminobenzenesulfonic acid and unidentified aromatic amines. Maximum current density of anode 0.59 Am −2 and power density of 0.12 Wm −2 were obtained under optimized conditions. As a result, decolouration of AO5 and chemical oxygen demand (COD) removal efficiency was 81 and 58%, respectively. These results revealed that the low-cost MFC assembly can offer significant potential for anaerobic decolouration of recalcitrant textile wastewater.

Raqba Raqba, Shumaila Rafaqat, Naeem Ali et al.

Journal of Water Process Engineering • 2022

Nabila S. Selim, Heba Hamed Maghrawy, Reham Fathy et al.

Journal of Radiation Research and Applied Sciences • 2020

The aim of the present work was to increase bacterial adhesion on anode via inducing membrane modifications to enhance textile wastewater treatment in Microbial Fuel Cell (MFC). Real textile wastewater was used in mediator-less MFCs for bacterial enrichment. The enriched bacteria were pre-treated by exposure to 1 KGy gamma radiation and were tested in MFC setup. Bacterial cell membrane permeability and cell membrane charges were measured using noninvasive dielectric spectroscopy measurements. The results show that pre-treatment using gamma radiation resulted in biofilm formation and increased cell permeability and exopolysaccharide production; this was reflected in both MFC performance (average voltage 554.67 mV) and decolorization (96.42%) as compared to 392.77 mV and 60.76% decolorization for non-treated cells. At the end of MFC operation, cytotoxicity test was performed for treated wastewater using a dermal cell line, the results obtained show a decrease in toxicity from 24.8 to 0 (v/v%) when cells were exposed to gamma radiation. Fourier-transform infrared (FTIR) spectroscopy showed an increase in exopolysaccharides in bacterial consortium exposed to increasing doses of gamma radiation suggesting that gamma radiation increased exopolysaccharide production, providing transient media for electron transfer and contributing to accelerating MFC performance. Modification of bacterial membrane prior to MFC operation can be considered highly effective as a pre-treatment tool that accelerates MFC performance.

Ting Xu, Qiuying Wang, Shijia Wu et al.

Journal of Cleaner Production • 2017

Beenish Saba, Birthe V. Kjellerup, Ann D. Christy

Bioresource Technology Reports • 2021

Chandrakant R. Holkar, Harshit Arora, Dibyadeep Halder et al.

International Biodeterioration & Biodegradation • 2018

Priyadharshini Mani, V. T. Fidal, Kyle Bowman et al.

Frontiers in Energy Research • 2019

More than 80 per cent of wastewater from industries is discharged into receiving water bodies without any pollution control. Microbial fuel cells (MFCs) are a promising technology for the simultaneous treatment of wastewater and electricity production. With regard to azo-dye containing wastewater (e.g. from textile manufacturing), the dye may be fed via the anode chamber containing electrochemically active bacteria or via the cathode chamber containing laccase enzyme as catalyst for oxygen reduction. This study investigated which of the two approaches is the best with regard to rate of decolourization of the dye (Acid orange 7), COD reduction and electricity production. The power density was higher for the MFCDye cathode (50±4 mW m-2, COD reduction 80.4±1.2%) compared with 42.5±2.6 mW m-2 (COD reduction 69±2%) for MFCDye anode. The time required for decolourization was longer in the MFCDye anode (Shewanella oneidensis) where only 20% decolourization was obtained after 24 h compared to 80% for the MFCDye cathode. The anodic dye degradation products were unstable when exposed to air resulting in regaining of colour. In case of degradation by laccase in the cathode chamber, the decolourization products were stable and simpler in chemical structure as determined by GC-MS. This work suggests that feeding azo dyes in cathode chambers of MFCs containing laccase is a better way of treating the dyes compared to the commonly used approach of feeding the dye in the anode chamber provided enzyme activity can be sustained.

Pimprapa Chaijak, Thanaphorn Rakkan, Nisa Paichaid et al.

Journal of Polymers and the Environment • 2024

Alfonz Kedves, Levente Sánta, Margit Balázs et al.

Journal of Hazardous Materials • 2019

The chronic responses of aerobic granular sludge (AGS) to the presence of graphene oxide nanoparticles (GO NPs) (5, 15, 25, 35, 45, 55, 65, 75, 85, and 95 mg/L of GO NPs for 7 days) during biological wastewater treatment processes were investigated. Bioreactor performance, extracellular polymeric substance (EPS) secretion, and microbial community characteristics were assessed. The results showed that the effects of GO NPs on bioreactor performances were dependent on the dose applied and the duration for which it was applied. At concentrations of 55, 75, and 95 mg/L, GO NPs considerably inhibited the efficiency of organic matter and ammonia removal; however, nitrite and nitrate removal rates were unchanged. Biological phosphorus removal decreased even when only low concentrations of GO NPs were used. The secretion of EPS, which could alleviate the toxicity of GO NPs, also changed. The increased amount of nanoparticles also resulted in significant changes to the bacterial community structure. Based on the amplicon sequencing of 16S rRNA genes, Paracoccus sp., Klebsiella sp., and Acidovorax species were identified as the most tolerant strains.

Sharjeel Waqas, Noorfidza Yub Harun, Muhammad Roil Bilad et al.

Membranes • 2022

A large amount of wastewater is directly discharged into water bodies without treatment, causing surface water contamination. A rotating biological contactor (RBC) is an attached biological wastewater treatment process that offers a low energy footprint. However, its unstable removal efficiency makes it less popular. This study optimized operating parameters in RBC combined with external membrane filtration (RBC-ME), in which the latter acted as a post-treatment step to stabilize the biological performance. Response surface methodology (RSM) was employed to optimize the biological and filtration performance by exploiting three parameters, namely disk rotation, hydraulic retention time (HRT), and sludge retention time (SRT). Results show that the RBC-ME exhibited superior biological treatment capacity and higher effluent quality compared to stand-alone RBC. It attained 87.9 ± 3.2% of chemical oxygen demand, 45.2 ± 0.7% total nitrogen, 97.9 ± 0.1% turbidity, and 98.9 ± 1.1% ammonia removals. The RSM showed a good agreement between the model and the experimental data. The maximum permeability of 144.6 L/m 2 h bar could be achieved under the optimum parameters of 36.1 rpm disk rotation, 18 h HRT, and 14.9 d SRT. This work demonstrated the effective use of statistical modeling to enhance RBC-ME system performance to obtain a sustainable and energy-efficient condition.